Cooperative role of cobalt and gallium under the ethanol steam reforming on Co/CeGaOx

The performance of gallium promoted cobalt-ceria catalysts for ethanol steam reforming (ESR) was studied using H₂O/C₂H₅OH = 6/1 mol/mol at 500 °C. The catalysts were synthetized via cerium-gallium co-precipitation and wetness impregnation of cobalt. A detailed characterization by N₂-physisorption, XRD, H₂-TPR and TEM allowed the normalization of contact time and rationalization of the role of each catalysts component for ESR. The gallium promoted catalyst, Co/Ce₉₀Ga₁₀O_x, was more efficient for the ethanol conversion to H₂ and CO₂, and the production of oxygenated by-products (such as, acetaldehyde and acetone) than Co/CeO₂. The catalytic performance is explained assuming that: (i) bare ceria is able to dehydrogenate ethanol to ethylene; (ii) Ce–O–Ga interface catalyzes ethanol reforming; (iii) both Ce–O–Co and Ce–O–Ga interfaces takes part in acetone production; and (iv) cobalt sites further allow C–C scission. It is suggested that a cooperative role between Co and Ce–O–Ga sites enhance the H₂ and CO₂ yields under ESR conditions.     

压裂水平井产能预测方法研究进展

水平井压裂技术在低渗透及非常规储层中得到了广泛应用,压裂后水平井的产能预测关系到油田开发方案的制定,因此,国内外学者对压后渗流模型的建立和求解方法做出了不懈的努力。本文详细回顾了国内外学者所建压裂水平井产能预测模型及求解方法,指出了不同模型和求解方法的优缺点,并展望了压裂水平井产能模型的发展方向。     

基于“校企协同”的制冷空调课程体系的构建

从制冷空调企业的现状出发,利用校企协同、产教融合的创新组织模式,整合暖通行业、企业和学校的资源优势,构建一套“协同创新”的制冷空调课程体系,从根本上提高建环专业学生工程素养和创新能力,以满足暖通行业、企事业单位对具有实践及创新能力的高素质应用型技术人才需求。     

Moving beyond ‘more crop per drop’: insights from two decades of research on agricultural water productivity

ABSTRACT

Concern over increasing water scarcity has led to the introduction of the concept of agricultural water productivity and an emphasis on interventions to achieve ‘more crop per drop’. Yet, a strong debate continues on how the concept is to be defined and used. Drawing largely from the irrigation literature, the origins of the concept and its methodological developments are reviewed, and its use in applied work over two decades is discussed. Based on this analysis of conceptual and applied research, key insights into the concept’s contributions and limitations are presented, as well as opportunities for further refinements.     

超高层劲性结构及大型机械设备立体协同施工技术

基于某超高层建筑群项目的主体施工阶段,对超高层劲性结构建筑群项目施工过程中可能遇到的问题,诸如大型机械立体协同、钢结构与钢筋连接节点优化、钢结构桁架层施工等重难点进行总结分析,并提出相应的解决方案以供探讨,可为同类型工程提供参考经验。     

Analysis of the patent cooperation network in global artificial intelligence technologies based on the assignees

Studying the distribution of the patent cooperation networks from the perspective of assignees provides a very important reference to improve the analysis of the market situation, master the layout of industrial technology and seek partners or mergers and acquisitions. This study uses the Derwent patent database and the patent metric approach to investigate the cooperative network structure of the assignees. The overall patent output in the artificial intelligence field on a global scale exhibited a rapid growth, and the proportion of cooperative patents significantly increased; the cooperation structure between the assignees was loose, and the innovation efficiency was low.     

The Territorial Impact Assessment of transport: the case of the Egnatia motorway system in the cohesion potential of Southeast Europe

Territorial Impact Assessment (TIA) is proposed as a critical tool in order to investigate the way policies affect spatial development and hence territorial cohesion. The paper introduces a TIA methodological model in relation to transport sector. The design of the methodological model is based on a quantitative evaluation framework that comprises a set of selected indicators applied in a cross-border area of southeast Europe, influenced by the operation of the Greek motorway system of Egnatia and its vertical axes. The indicators are grouped into three main fields of TIA, i.e. transport intermodality, polycentric spatial organization and cross-border territorial cooperation. The TIA’s indicators are approximated by quantitative analysis. The procedure concludes to an overall composite indicator measuring the ‘level of territorial cohesion’ along with some core results and the expected added value. It also highlights some key technical aspects about the routines used and proceeds to suggestions for further refinement.     

Policy reforms and productivity change in the judiciary system: a cost function approach applied to time series of the Dutch judiciary system between 1980 and 2016

The judiciary is constantly undergoing change in order to respond to a wide range of social developments that have brought the sector under increasing pressure. In order to deal with the constant call for enhancing budgets, different policy measures have been taken to downsize the appeal to the judiciary and to improve productivity. One of the central questions hereby is whether these measures have actually contributed to a more productive sector. This paper focuses on the development of productivity in the judiciary and how policy measures have affected productivity. In this empirical analysis, we apply a cost function model to time series data of the Dutch judiciary between 1980 and 2016. The results show a dramatic decline of productivity over the entire period (?50%), in spite of various policy measures. The year 2001 can be regarded as a turning point, as since then productivity has remained more or less stable. It seems that this is largely due to the establishment of the Council for the Judiciary and the associated increase in (financial and operational) autonomy for the judiciary. Another striking result is that technical change is biased toward using more personnel through time.     

球磨过程中介质群运动区域划分方法研究

球磨过程中介质群运动状态变化对物料的破碎效率影响极大，通过对介质群运动状态进行区域划分，探究不同球磨工况下的介质群运动区域特征更能有效揭示介质群对物料的破碎方式和有效破碎区域。针对理论划分介质群运动区域过于理想、单一，试验追踪法成本过高的问题，提出了一种介质群运动区域划分的新方法-EDEM网格划分法。首先把筒体的横截面划分为若干个微元，利用数理统计的方法得到介质群位置概率分布函数，获取介质群运动速度区域分布图和碰撞特性区域分布图。然后给出了回转运动、螺旋运动及复合颤振运动三种工况下介质群运动区域的划分实例，并与试验追踪法对比，验证了EDEM网格划分法的准确性和有效性。最后通过粉磨试验中进料的破碎速率和微细颗粒产率探讨了介质群运动区域特性对颗粒的破碎方式和有效破碎区域的影响效果。本研究为优化球磨过程的影响因素和操作参数提供了一种快捷、有效的方法。